Let Ω ⊂ ℝn, n ≥ 2, be a bounded domain and let α < n − 1. Motivated by Theorem I.6 and Remark I.18 of [Lions P.-L., The concentration-compactness principle in the calculus of variations. The limit case. I, Rev. Mat. Iberoamericana, 1985, 1(1), 145–201] and by the results of [Černý R., Cianchi A., Hencl S., Concentration-Compactness Principle for Moser-Trudinger inequalities: new results and proofs, Ann. Mat. Pura Appl. (in press), DOI: 10.1007/s10231-011-0220-3], we give a sharp estimate of the exponent concerning the Concentration-Compactness Principle for the embedding of the Orlicz-Sobolev space W 01 L n logα L(Ω) into the Orlicz space corresponding to a Young function that behaves like exp t n/(n−1−α) for large t. We also give the result for the case of the embedding into double and other multiple exponential spaces.